From the tooltip in the search bar:
Use a dash to exclude the coins matching with a word for expression.
Example: Martin Luther -King
That example works fine. What doesn't work is if you only write
-King
For example, if I use any other search criteria for issuer, metal, year, etc. (or none at all) and just want to exclude something like a denomination, it doesn't work. Little example:
But this trick/workaround doesn't work for all cases that might be relevant. So it would be easier if it just works without anything else in the search bar too.